formula of moisture content
|3. How to measure
the water content
|4. Interpretation and relation to flowability of moisture content|
Most powders have the capacity to pick-up water and therefore are containing a certain amount of water. This water can come from the manufacturing process, for example the amount of water remaining after a drying step, or can migrate to the material later, for example by submitting the powder to a humid air. The mass of water contained in a mass of material is called the moisture content or water content.
The moisture content should not be confused with the water activity.
The ratio in between the water contained in the material and the material weight gives the moisture content :
u = mw/ms
u = moisture content (kg of water / kg of material)
mw = mass of water content in the solid weight considered (kg of water)
ms = mass of dry solid (kg of material)
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The most widespread method to measure the water content of a powder sample is to use a oven that will heat up and then dry the sample. The sample is precisely measured before and after drying (in defined conditions) so that the difference gives the amount of water evaporated, thus the amound of water that was in the sample.
mw = ms_wet - ms_dry
Equation 2 : mass of water in a sample
mw = mass of water content in the solid weight
considered (kg of water)
ms_wet = mass of wet solid (kg of material)
ms_dry = mass of dry solid (kg of material)
One drawback of this method is that it will not be very accurate if the material is also containing some volatile compounds that will also be removed during heating.
In this case, the Karl-Fischer titration can be more adapted as it allows to analyse only water.
The "humidity of a powder", or rather its moisture content, is often mentioned as a usual root cause of bad flowability of powder. Indeed, if the moisture content is too high, a solid will be prone to caking, clumping, generally bad flowability. The water content is then high enough to create small water bridges in between particles and modify their flow behavior.
It is possible with a powder rheometer to measure the relation in between the "flowability" and the water activity. Powders of different water content are measured, if the energy to make them flow changes radically at a certain moisture content, then the powder is sensitive.
One important effect of water on powders is that it can play the role of a plasticize, thus modifying the glass transition temperature Tg if the powder is made of an amorphous material (polymer, in plastic industries, but also in food industries). The glass transition temperature varies with the moisture content which means that, when submitted to a temperature T, the water content can bring the Tg below T and thus makes the material sticky changing radically it flow behavior.
Different suppliers have developed bench scale moisture content testers allowing to make quick measurement of moisture content of a sample.
The company PCE is commercializing such instruments : https://www.pce-france.fr/mesureurs/analyseurs-humidite.htm
(Note that PowderProcess.net has no link with this company)